Common Phases for the TCOX Database

Corundum (Al₂O₃), Eskolaite (Cr₂O₃), Hematite (Fe₂O₃), Karelianite (V₂O₃), Tistarite (Ti₂O₃), CoTiO₃, Ilmenite (FeTiO₃), Geikielite (MgTiO₃), Pyrophanite (MnTiO₃), NiTiO₃. The ilmenite ((Co,Fe,Mg,Mn,Ni)TiO₃) crystal structure consists of an ordered derivative of the corundum structure. In corundum all cations are identical, but in ilmenite Me+2 and Ti+4 occupy different sublattices. Both the disordered and ordered end-members are described in the CORUNDUM phase in the database. Anti-site occupancy in the ilmenite structure is not modeled.

Lime (CaO), CoO, Wustite (FeO), Periclase (MgO), Manganosite (MnO), Bunsenite (NiO), Baria (BaO).

Alabandite (MnS), Oldhamite (CaS), MgS, GdS, LaS, ZrS, BaS.

Grossular (Ca₃Al₂(SiO₄)₃), Uvarovite (Ca₃Cr₂(SiO₄)₃), Spessartine (Mn₃Al₂(SiO₄)₃), Goldmanite (Ca₃V₃(SiO₄)₃). Other minerals part of the Garnet structure, such as Pyrope and Almandine, are not part of the database since they are not stable at ambient pressure. Included in the GARNET model are also the (Gd,Y,Yb)₃(Al,Fe)₅O₁₂ descriptions.

This is the hexagonal La₂O₃ and Gd₂O₃ modifications.

This is monoclinic Gd₂O₃.

This is Bixbyite (Mn₂O₃) and cubic Gd₂O₃ , Y₂O₃ and Yb₂O₃.

This is hexagonal La₂O₃, Gd₂O₃, Y₂O₃ and Yb₂O₃.

This is x-La₂O₃ and high-temperature cubic Gd₂O₃.

Gehlenite (Ca₂Al₂SiO₇), Fe-Gehlenite (Ca₂Fe₂SiO₇), Åkermanite (Ca₂MgSi₂O₇), Fe-Åkermanite (Ca₂FeSi₂O₇), CaCoSi₂O₇, Bennesherite (Ba₂FeSi₂O₇), and Ba₂MgSi₂O₇.

Calcio-olivine (Ca₂SiO₄), Co₂SiO₄, Fayalite (Fe₂SiO₄), Forsterite (Mg₂SiO₄), Tephroite (Mn₂SiO₄), Ni₂SiO₄, Kirschsteinite (CaFeSiO₄), Monitcellite (CaMgSiO₄), Glaucochroite (CaMnSiO₄), Liebenbergite (Ni₂SiO₄)

Pseudobrookite (Fe₂TiO₅), Karrooite (MgTi₂O₅), Ti₃O₅, Al₂TiO₅, CoTi₂O₅, Armalcolite ((Fe,Mg)Ti₂O₅), MnTi₂O₅.

Low clino-enstatite (MgSiO₃), low clino-diopside (CaMgSi₂O₆).

Clino-enstatite (MgSiO₃), clino-ferrosilite (FeSiO₃), diopside (CaMgSi₂O₆), Niopside (CaNiSi₂O₆), Pigeonite ((Mg,Fe,Ca)Si₂O₆), Hedenbergite (CaFeSi₂O₆).

Enstatite (MgSiO₃), ortho-Diopside (CaMgSi₂O₆).

Proto-enstatite (MgSiO₃), proto-diopside (CaMgSi₂O₆).

Pyrrhoitite (FeS), CoS, CrS, NbS, NiS, TiS, VS.

Rutile (TiO₂), Pyrolusite (MnO₂), high-temperature VO₂.

Tetragonal Hausmannite (Mn₃O₄).

The cubic AB2O4-type spinel. Many end-members, solid solutions and combinations are described in the SPINEL phase: Magnetite (Fe₃O₄), cubic Hausmannite (Mn₃O₄), Guite (Co₃O₄), Spinel (MgAl₂O₄), Cuprospinel (CrFe₂O₄), Chromite (FeCr₂O₄), Hercynite (FeAl₂O₄), Coulsonite (FeV₂O₄), Vuorelainenite (MnV₂O₄), Magnesiocoulsonite (MgV₂O₄), CoV₂O₄, NiV₂O₄, Galaxite (MnAl₂O₄), Jacobsite (MnFe₂O₄), Magnesiochromite (MgCr₂O₄), Magnesioferrite (MgFe₂O₄), Manganochromite (MnCr₂O₄), Thermaerogenite (CuAl₂O₄), Ulvöspinel (TiFe₂O₄), Trevorite (NiFe₂O₄), NiAl₂O₄, CoAl₂O₄, CoFe₂O₄, FeCo₂O₄, CoMn₂O₄, CuMn₂O₄, MgMn₂O₄, NiMn₂O₄, Co₂TiO₄, Mg₂TiO₄, MgTi₂O₄, MnTi₂O₄, Mn₂TiO₄, Ni₂TiO₄, LiAl₅O₈, LiFe₅O₈, LiMn₂O₄, Li₄Mn₅O₁₂, and Li₄Ti₅O₁₂.