About Paraequilibrium

A paraequilibrium is a partial equilibrium where one interstitial component (such as carbon C and nitrogen N) in a multicomponent alloy can diffuse much faster than the other components (the substitutional elements, including the matrix element and alloying elements). The chemical potential for the interstitial component in two partially equilibrated phases is equal in such a case, but this is not true for the other components. In such a paraequilibrium state, it is possible to have a transformation that is partly without partitions, where a new phase of the mobile component can form with different content but where the slowly diffusing components retain their compositions.

A paraequilibrium calculation is useful when, for example, you want to study phase transformations in systems with large differences in the diffusivities of different elements. Transformations occurring under paraequilibrium states can be much more rapid than if full local equilibrium holds at the phase interface.

Calculating a Paraequilibrium