Continuity Equation
Let be the PSD of a precipitate phase,
the number of particles per unit volume,
the mean radius and
the particle volume fraction, is expressed as
[Eq. 1]
[Eq. 2]
[Eq. 3]
The time evolution of follows the continuity as in Langer and Schwartz [1980Lan].
[Eq. 4]
Where is the growth rate of a particle of size
, and
is the distributed nucleation rate, which is defined by
[Eq. 5]
where is the nucleation rate.
Reference
[1980Lan] J. S. Langer, A. J. Schwartz, Kinetics of nucleation in near-critical fluids. Phys. Rev. A. 21, 948–958 (1980).