Precipitation Morphology

As the spherical particle is the default morphology, for precipitations within the grain, three non-spherical shapes are considered: cuboid, plate and needle.

Growth

Homogeneous Nucleation

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Cuboid

The cuboid shape is described by a supersphere. Cuboids have six faces, which form a convex polyhedron.

Figure 1: Cuboids have six faces, which form a convex polyhedron.

The cuboid shape is described by a supersphere

cuboid shape is described by a supersphere

with p=2 being spherical shape. The larger the p, the more cubic the shape. Sometimes it is useful to define the cubical character as

cubical character

Which gives a spherical shape when eta=1 , and a cubic shape when eta=sqrt{2}.

Plate

The plate is described as oblate spheroid. Oblate spheroids have rotational symmetry around an axis from pole to pole.

Figure 2: Oblate spheroids have rotational symmetry around an axis from pole to pole.

The plate is described as oblate spheroid

plate is described as oblate spheroid

with aspect ratio

aspect ratio for a plate morphology

Needle

The needle shape is described as prolate spheroid. A prolate spheroid is a surface of revolution obtained by rotating an ellipse about its major axis.

Figure 3: A prolate spheroid is a surface of revolution obtained by rotating an ellipse about its major axis.

The needle shape is described as prolate spheroid

needle shape is described as prolate spheroid

with aspect ratio

aspect ratio for a needle morphology

Precipitations at a Grain Boundary, Edge or Corner

For precipitations at a grain boundary, grain edge, or grain corner, non-spherical particles are considered based on wetting angle.

Heterogeneous Nucleation

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